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61.
Liu Dejia Guo Rui Hu Yong Shen Mingxue Tang Yanchuan Zhao Longzhi Li Deying Wang Xiangjie 《Metals and Materials International》2020,26(6):854-866
Metals and Materials International - High-entropy alloys having excellent properties are particularly suitable for the application as the filler metals in welding. In the present study,... 相似文献
62.
Chong Shen Minjing Shang Hong Zhang Yuanhai Su 《American Institute of Chemical Engineers》2020,66(2):e16841
In this work, we report a simple and inexpensive UV-LEDs based photomicroreactor assembly constructed by commercially available components. The photoisomerization of norbornadiene to quadricyclane was selected to validate this novel photomicroreactor design. Mass transport limitation was eliminated and indicated by dimensionless numbers Fo and Da II, and photons loss was evaluated considering the absorption and reflection of the microreactor walls. The solvents, photosensitizers, and light sources selections were optimized for achieving better photochemical performance and mechanistic insights. The detailed comparison between the high-pressure mercury arc lamp and the UV-LEDs strip revealed great potential of UV-LEDs as appealing light source for photochemical transformations. Moreover, the reaction mechanism was thoroughly discussed and illustrated by the Jablonski diagram indicating electronic states transitions. According to possible intermediate steps, a kinetic model was proposed with the reaction rate constant being correlated with the photon flux, which is valuable for process optimization and further understanding reaction mechanisms. 相似文献
63.
Xiaoqin Zhang Shugang Ma Ang Shen Jin Zhu Zhisen Shen Jinggang Wang Xiaoqing Liu 《应用聚合物科学杂志》2020,137(44):49365
Poly(butylene terephthalate-co-butylene 2,5-furandicarboxylate) copolyesters (PBTFs) were synthesized from 1,4-butanediol, dimethyl terephthalate (DMT), and 2,5-furandicarboxylic acid (FDCA) by a two-step polymerization method. Their chemical structures were confirmed by Fourier-transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and carbon nuclear magnetic resonance before thermal properties were explored with differential scanning calorimeter and thermogravimetric analyzer. Results showed that PBTFs changed from semi-crystalline to completely amorphous when the content of FDCA unit was increased to 45 mol% at first, and then became crystallographic again with the further increment of FDCA unit to 75 mol%. For their mechanical properties, the tensile modulus and strength showed the similar trend, decreasing firstly and then increasing later. Their barrier to carbon dioxide and oxygen became better with the increasing of furan content due to the rigidity and higher polarity of furan ring. The performance of PBTFs copolyesters was investigated clearly, and the relative content of FDCA and DMT can be adjusted to satisfy different performance requirements. 相似文献
64.
Rizwan Ullah Khan Haojie Yu Li Wang Lisong Teng Zain-ul-Abdin Ahsan Nazir Shah Fahad Tarig Elshaarani Fazal Haq Di Shen 《应用聚合物科学杂志》2020,137(46):49424
The development of safe drug carriers is cardinal in cancer therapy, which can target the cancer cells and release the loaded drug on-demand without damaging the healthy cells of the body. In our work, we synthesized three different biodegradable polymers, poly[(ethyl aminobezoate) (ethyl glycinato) phosphazenes] (PABGPs), in different mole ratio of side groups. The successful synthesis of these PABGPs was confirmed by 1H NMR, 31P NMR, FT-IR, and gel permeation chromatography. These PABGPs were fabricated into drug (camptothecin, CPT, a hydrophobic anticancer drug) loaded nanoparticles. These drug-loaded nanoparticles showed good drug release behaviors under normal physiological conditions (pH 7.4 and temperature 37°C). These PABGPs-based nanoparticles may find their application as effective drug carriers for cancer therapy. 相似文献
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Minquan Sun Shuling Shen Zhujun Wu Zhihong Tang Jiaping Shen Junhe Yang 《Ceramics International》2018,44(7):8125-8132
A novel rice spike-like g-C3N4/TiO2 nanowire heterojunctions are fabricated by hydrothermal treating Na2Ti3O7 ultralong nanotubes in the presence of g-C3N4. The presence of g-C3N4 promotes the hydrolysis of Na2Ti3O7 ultralong nanotubes. The partially replaced O of TiO2 by N from g-C3N4 leads to the formation of a tight-binding interface between one dimensional TiO2 and two dimensional g-C3N4, which is crucial for fast and effective transfer of photogenerated electrons in heterostructured photocatalysts. As a result, the g-C3N4/TiO2 nanowire heterojunctions exhibit excellent visible-light photocatalytic activity. The kinetic constant (k) of g-C3N4/TiO2 (0.024?min?1) for degradation of methylene blue under visible light irradiation is 1.85 and 4 times than that of pure g-C3N4 and P25, respectively. 相似文献
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